• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    This invention relates to chemical methods of protecting plants. The purpose of the invention is to reduce the phytotoxicity of the method with respect to sorghum plants, pretreatment of seeds with an antidote, a benz / acetonitrile derivative of the formula SbHbS (= L-0-CH2- [SzN502]) (CN) in the amount of 0.75-4 g / kg seed and pre-emergence tillage in sorghum crops with the herbicide -N-
    公开号:SU1715187A3
    申请号:SU792807710
    申请日:1979-08-31
    公开日:1992-02-23
    发明作者:Щепански Хенри；Мартин Хенри；Фери Вернер；Пассиотас Георг
    申请人:Циба-Гейги Аг (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to chemical methods of plant protection, specifically to a method of controlling weeds in sorghum crops by treating plants or their bioton with the N- (1-methyl-2-methoxy-methyl) -N (chloroacetyl) -2-ethyl-6- herbicide herbicide. methaniline (metolachlor), and seed treatment with an antidote derivative of methoxyiminobenzyl cyanide.
    The purpose of the invention is to reduce the phytotoxicity of the method with respect to sorghum plants.
    PRI me R 1. Synthesis of N- (1,3-dioxolan-2-yl-methoxy) -iminobenzoacetonitrile (compound I).
    To a suspension of 33.6 g (0.2 mol) of sodium salt-phenylacetonitriloxime in 140 ml of dimethyl sulfoxide was added dropwise with stirring and cooling in an ice-water bath of 33.8 g (0.2 mol) of 2-bromo-methyl-1,3- dioxolane. Then the reaction mixture is stirred for 4 hours at 60-70 ° C, extracted with 600
    ml of ether and washed three times with 2% NaOH solution. The ether extract is dried with sodium sulfate, filtered and evaporated. The residue was recrystallized from hexane and 44.1 g (95% of theory) of compound I were obtained as colorless crystals with m.p. 67 ° C.
    PRI mme R 2. Antidote activity of compound I.
    Sorghum seeds (100 g) and antidote were placed in a glass jar. The vessel is shaken and rotated to ensure good displacement.
    In 5-10 days after seed dressing, they are sown in a greenhouse in plastic pots with a diameter of 11 cm or containers 5 cm high (25x17 cm), which are filled with sandy loam. Dose of seeds is 10-20 kg / ha. The surface of the land is then treated with a herbicide by spraying.
    Antidote activity is determined 21 days after application of the herbicide. The data presented in the table.
    Thus, the proposed method has high efficiency at low consumption rates.
    权利要求:
    Claims (1)
    [1]
    Invention Formula
    A method for controlling weeds in sorghum crops by pretreatment of seeds with an antidote derived from benzacetonitrile and pre-emergence tillage with the herbicide M- {1-methyl-2-methoxy-ethyl-6-chloroacetyl-2-ethyl-6-methylaniline in a dose
    1.5-2.5 kg / ha. different temcht. In order to reduce the phytotoxic effect of the sorghum herbicide, a compound of the formula is used as a benzacetonitrile derivative.
    L C-SI.
    at II / o
    H-0-CH-
    0
    in the amount of 0.75-4 g / kg seed n.
     Compound A - anhydride, 8-naphthalic acid. Compound B - cysnometaxyminobenzeneetpiitrill
    类似技术:
    公开号 | 公开日 | 专利标题
    SU1715187A3|1992-02-23|Method for controlling weeds in sorghum crops
    SU1324572A3|1987-07-15|Method of protecting cultivated plants from unwanted effect of herbicide
    RU1783963C|1992-12-23|Method for control of phytopathogenic microorganisms
    US3984435A|1976-10-05|Herbicidal N-substituted-Δ1 -tetrahydrophthalimide
    KR0147844B1|1998-08-17|Cyclic amide compounds and herbicides
    CA1179680A|1984-12-18|Herbicidal n-haloacetyl-2-alkyl-6-acylanilines
    US4849438A|1989-07-18|1,2-benzoisothiazol-3|-one 1,1-dioxide, ion|,2-hydroxy-N,N,N-trimethyl-ethanaminium which is plant protection agent for control of fungi and bacteria
    CA1174866A|1984-09-25|Plant growth regulating cyano-phenyl-acetamidederivatives
    RU1799242C|1993-02-28|Method of struggle against insects and ticks
    US2893855A|1959-07-07|N-1-napthylchlorophthalamic herbicides
    EP0382463B1|1995-04-26|Maleimide compounds and fungicides containing them
    GB1077180A|1967-07-26|Novel n-|-imides
    EA000109B1|1998-08-27|Triazine derivatives
    ES262301A1|1961-01-16|N-trichloromethylthiohydantoins
    KR840000846B1|1984-06-19|Process for the preparation of n-|-n-alkoxyacetylanilines
    US4188203A|1980-02-12|Herbicidal and phytohormonal amidoximes
    US4035387A|1977-07-12|1,3-Dithiol-2-ylidene malonic esters
    US3574594A|1971-04-13|Phenylacetonitriles as pre-emergence herbicides
    US4063921A|1977-12-20|Method for the cultivation of plants employing α-cyano-α-hydroxyimino-acetamide derivatives
    US4208204A|1980-06-17|3-Hydroxy-3-methylglutaric acid monoamide and derivatives thereof
    PL111161B1|1980-08-30|Herbicide
    US3859444A|1975-01-07|Methods of killing bacteria using alkylthiosemicarbazides
    US3988328A|1976-10-26|5-Amino-2,3,7,8-tetrathiaalkane-1,9-dioic acids, esters and salts
    US3544305A|1970-12-01|Herbicidal n-formyl alpha-haloacetanilides
    US4251261A|1981-02-17|2-Chloro-4-trifluoromethyl-5-thiazolecarboxylic acids and derivatives
    同族专利:
    公开号 | 公开日
    JPS599546B2|1984-03-03|
    CS212243B2|1982-03-26|
    US4269775A|1981-05-26|
    ZA794622B|1981-04-29|
    DE2966641D1|1984-03-15|
    EP0011047A3|1980-09-03|
    UA5584A1|1994-12-28|
    IE791662L|1980-03-01|
    JPS58140003A|1983-08-19|
    AU531302B2|1983-08-18|
    IL58150D0|1979-12-30|
    EP0011047A2|1980-05-14|
    HU193495B|1987-10-28|
    IE48817B1|1985-05-29|
    HU182942B|1984-03-28|
    DD147904A5|1981-04-29|
    JPS5535093A|1980-03-11|
    EP0011047B1|1984-02-08|
    IL58150A|1985-07-31|
    AU5047379A|1980-03-06|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    WO2013130392A1|2012-03-01|2013-09-06|Fmc Corporation|Safening fluthiacet-methyl on sorghum with 2,4-d amine|US3131509A|1961-05-08|1964-05-05|Spencer Chem Co|Compositions and methods for reducing herbicidal injury|
    DE2219802C2|1972-04-22|1982-01-28|Basf Ag, 6700 Ludwigshafen|Oxime ethers and herbicides containing them|
    US3980693A|1972-09-06|1976-09-14|Bayer Aktiengesellschaft|N--carbamic acid oxime esters|
    CH624552A5|1975-09-04|1981-08-14|Ciba Geigy Ag|
    US4152137A|1975-09-04|1979-05-01|Ciba-Geigy Corporation|Phenylglyoxylonitrile-2-oxime-cyanomethyl ether as a crop safener|
    CH632130A5|1977-03-02|1982-09-30|Ciba Geigy Ag|Compositions on the basis of oxime ethers, oxime esters or oxime carbamates which are suitable in agriculture for crop protection|
    US4269775A|1978-09-01|1981-05-26|Ciba-Geigy Corporation|Oxime derivatives for protecting plant crops|IT1110460B|1977-03-02|1985-12-23|Ciba Geigy Ag|PRODUCTS THAT PROMOTE THE GROWTH OF PLANTS AND PRODUCTS THAT PROTECT PLANTS BASED ON BODY ETHERS AND BODY ESTERS THEIR PREPARATION AND USE|
    US4532732A|1978-09-01|1985-08-06|Ciba-Geigy Corporation|Oxime derivatives for protecting plant crops|
    US4269775A|1978-09-01|1981-05-26|Ciba-Geigy Corporation|Oxime derivatives for protecting plant crops|
    US4497648A|1978-09-01|1985-02-05|Ciba-Geigy Corporation|Oxime derivatives for protecting plant crops|
    US4490167A|1979-08-06|1984-12-25|Ciba-Geigy Corporation|Oxime derivatives of diphenyl ethers and their use in herbicidal compositions|
    EP0077854A1|1981-10-22|1983-05-04|Union Carbide Corporation|Herbicidal halogenated aromatic aminooxyacetic acid compounds and methods of use|
    JPS58116450A|1981-12-29|1983-07-11|Nippon Soda Co Ltd|5-phenylcyclohexenone derivative, its preparation and selective herbicide|
    DE3206235A1|1982-02-20|1983-09-01|Bayer Ag, 5090 Leverkusen|SUBSTITUTED OXIMINOACETANILIDES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS A PEST CONTROL|
    DE3360154D1|1982-03-15|1985-06-05|Ciba Geigy Ag|Oxime ethers, process for their preparation, compositions containing the oxime ethers and their use|
    EP0092517B1|1982-04-16|1986-03-12|Ciba-Geigy Ag|Oxime ethers, process for their preparation, agents containing these compounds and their use|
    DE3481031D1|1983-04-12|1990-02-22|Ciba Geigy Ag|HERBICIDAL AGENT.|
    EP0138773B1|1983-10-18|1990-08-29|Ciba-Geigy Ag|Use of quinoline derivatives for the protection of crop plants|
    US4938796A|1987-07-06|1990-07-03|Ici Americas Inc.|Herbicidal compositions of acylated 1,3-dicarbonyl herbicides and antidotes therefor|
    US5201933A|1988-08-01|1993-04-13|Monsanto Company|Safening herbicidal benzoic acid derivatives|
    YU48319B|1988-08-01|1998-05-15|Monsanto Company|SAFETY HERBICIDE DERIVATIVES OF BENZOIC ACIDS|
    US5527762A|1990-12-12|1996-06-18|Zeneca Limited|Antidoting herbicidal 3-isoxazolidinone compounds|
    DE4206353A1|1992-02-29|1993-09-02|Basf Ag|CYANOOXIMETHER, METHOD FOR THE PRODUCTION THEREOF, MEANS CONTAINING IT AND THE USE THEREOF|
    US6919375B1|1996-01-23|2005-07-19|Shionogi & Co., Ltd.|Sulfonated amino acid derivatives and metalloproteinase inhibitors containing the same|
    KR100338857B1|1996-01-23|2002-05-30|시오노 요시히코|Sulfonated amino acid derivatives and metalloproteinase inhibitors containing the same|
    US5756545A|1997-04-21|1998-05-26|Warner-Lambert Company|Biphenysulfonamide matrix metal alloproteinase inhibitors|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    CH925278|1978-09-01|LV930416A| LV5650A3|1978-09-01|1993-05-25|Seduction for Sickness in Soros Faces|
    LTRP1284A| LT2613B|1978-09-01|1993-09-29|THE FIGHT AGAINST PICTURE FIGHT ON SORG'S PASELS|
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